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LIX84‐Iを含浸した相互結合球状細孔をもつ高分子粒子によるニッケル(II)の抽出特性
http://hdl.handle.net/10458/4582
http://hdl.handle.net/10458/4582e6e259a0-86fd-48d4-8f2d-7c709c72d207
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Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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公開日 | 2013-08-19 | |||||||||||||
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タイトル | Extraction Properties of Nickel(II) with Polymeric Particles with Interconnected Spherical Pores Impregnating with LIX84-I | |||||||||||||
言語 | en | |||||||||||||
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タイトル | LIX84‐Iを含浸した相互結合球状細孔をもつ高分子粒子によるニッケル(II)の抽出特性 | |||||||||||||
言語 | ja | |||||||||||||
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言語 | eng | |||||||||||||
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資源タイプ | journal article | |||||||||||||
著者 |
清山, 史朗
× 清山, 史朗× 武井, 孝行× 吉田, 昌弘× 塩盛, 弘一郎
WEKO
5570
× Kitabayashi, Takuro× Sana, Takashi |
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内容記述タイプ | Abstract | |||||||||||||
内容記述 | 1-(2-hydroxyl-5-nonyphenyl) ethanone oxime (LIX84-I) was impregnated into polymeric particles with interconnected spherical pores by the solvent evaporation method. Divinylbenzene was used as a wall material and polymerized in the organic phase of a (W/O/W) emulsion by free radical polymerization. The diameter of the polymeric particles was almost constant at around 208±26μm. The impregnated yield of LIX84-I in the polymeric particles was higher than 80% in all preparation conditions. The extraction of Ni(II) with the polymeric particles impregnated with LIX84-I sharply increased at pH values higher than 6. It is confirmed that three molecules of LIX84-I reacted with one Ni(II) ion by quantitative analysis of the relationship between the maximum amounts of Ni(II) extracted and the amount of LIX84-I impregnated in the polymeric particles. The extraction rate of Ni(II) was effectively accelerated by the presence of the interconnected-spherical pores in the inside of the polymeric particles. | |||||||||||||
言語 | en | |||||||||||||
書誌情報 |
en : Solvent Extraction Research and Development, Japan 巻 20, p. 137-147, 発行日 2013-04 |
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出版者 | 日本溶媒抽出学会 | |||||||||||||
言語 | ja | |||||||||||||
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出版者 | JAPAN ASSOCIATION OF SOLVENT EXTRACTION | |||||||||||||
言語 | en | |||||||||||||
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収録物識別子タイプ | ISSN | |||||||||||||
収録物識別子 | 13417215 | |||||||||||||
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出版タイプ | VoR |