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Preparation of Large Size Microcapsules Containing Tri-n-octylamine by In situ Polymerization Combined with a Gel Inclusion Method and Their Extraction Behavior
http://hdl.handle.net/10458/3720
http://hdl.handle.net/10458/3720a192bcf9-2870-4212-93e1-534a8abb3c46
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Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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公開日 | 2012-05-31 | |||||||||||||
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タイトル | Preparation of Large Size Microcapsules Containing Tri-n-octylamine by In situ Polymerization Combined with a Gel Inclusion Method and Their Extraction Behavior | |||||||||||||
言語 | en | |||||||||||||
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言語 | eng | |||||||||||||
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資源タイプ | journal article | |||||||||||||
著者 |
塩盛, 弘一郎
× 塩盛, 弘一郎
WEKO
5570
× Saeki, Katsuyuki× Sana, Takashi× Kiyoyama, Shiro× Yoshida, Masahiro× Hatate, Yasuo |
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内容記述タイプ | Abstract | |||||||||||||
内容記述 | Large size microcapsules containing tri-n-octylamine (TOA) with a diameter of larger than 2 mm were prepared by in situ polymerization with a gel inclusion of an organic droplet. A copolymer of styrene and divinylbenzene was used as the capsule wall material. When the concentration of TOA was high, the structure of the microcapsules was mono-cored with a thin wall and large cavity. However, at low TOA concentration, the structure changed to a matrix type filled with the copolymer. The TOA content in the microcapsules increased linearly with the initial TOA concentration in the organic phase until 60wt%. The extraction of acetic acid into the microcapsules was successfully carried out. It was possible to reuse the microcapsules 4 times and the extracted amount of acetic acid into the microcapsules was constant during their reuse. | |||||||||||||
言語 | en | |||||||||||||
書誌情報 |
en : Solvent Extraction Research and Development, Japan 巻 17, p. 215-224, 発行日 2010 |
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出版者 | Japan Association of Solvent Extraction | |||||||||||||
言語 | en | |||||||||||||
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出版タイプ | VoR |