{"created":"2023-05-15T10:01:38.285853+00:00","id":6262,"links":{},"metadata":{"_buckets":{"deposit":"e3488ba4-f5ae-4f29-b27d-28bec3881221"},"_deposit":{"created_by":5,"id":"6262","owner":"5","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"6262"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00006262","sets":["73","73:27"]},"author_link":["5573","5571","5570","5572","20200"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-04","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"67","bibliographicPageStart":"55","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"Ars Separatoria Acta"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Microcapsules containing tri-n-octylamine as an extractant with the diameter\nof less than 25μm were prepared by using SPG membrane emulsification and insitu\npolymerization method. The morphologies of microcapsules, the encapsulation\nefficiencies of tri-n-octylamine, the extraction properties of palladium （II） from\nhydrochloric acid solution and the back extraction properties of palladium （II） from\nmicrocapsules were investigated. The average diameter of obtained microcapsules\nwas about half of the pore diameter of SPG membrane. The encapsulation\nefficiency of tri-n-octylamine was approximately 100% for all the microcapsules\nprepared in this study. Therefore, it can be said that there was practically no loss of\ntri-n-octylamine during the preparation of microcapsules. All microcapsules\nprepared in this study reached forward extraction equilibrium within 5 minutes and\nthe forward extraction ratio reached nearly 1. The back extraction of palladium （II）\nfrom microcapsules was carried out using 0.1M-hydrochloric acid solution\ncontaining a prescribed amount of thiourea. The back extraction occurred promptly\nand the back extraction ratio was high enough to elute all palladium （II） out from\nthe microcapsules. Furthermore, by repeating forward and back extraction\nexperiments, the durability of microcapsules was examined. From the result, it can\nbe said that tri-n-octylamine was encapsulated rigidly and there was no leakage\nduring extraction and back extraction experiment. Thus it seemed that the\nmicrocapsules were capable to be used in a repeated operation.","subitem_description_type":"Abstract"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"南畑, 孝介","creatorNameLang":"ja"},{"creatorName":"ミナミハタ, コウスケ","creatorNameLang":"ja-Kana"},{"creatorName":"Minamihata, Kosuke","creatorNameLang":"en"}],"familyNames":[{"familyName":"南畑","familyNameLang":"ja"},{"familyName":"ミナミハタ","familyNameLang":"ja-Kana"},{"familyName":"Minamihata","familyNameLang":"en"}],"givenNames":[{"givenName":"孝介","givenNameLang":"ja"},{"givenName":"コウスケ","givenNameLang":"ja-Kana"},{"givenName":"Kosuke","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"20200","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kiyoyama, Shiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5571","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"0000000106573887","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/0000000106573887"}],"affiliationNames":[{"affiliationName":"宮崎大学","affiliationNameLang":"ja"},{"affiliationName":"University of Miyazaki","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Shiomori, Koichiro","creatorNameLang":"en"},{"creatorName":"塩盛, 弘一郎","creatorNameLang":"ja"},{"creatorName":"シオモリ, コウイチロウ","creatorNameLang":"ja-Kana"},{"creatorName":"Shiomori, Kouichiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Shiomori","familyNameLang":"en"},{"familyName":"塩盛","familyNameLang":"ja"},{"familyName":"シオモリ","familyNameLang":"ja-Kana"},{"familyName":"Shiomori","familyNameLang":"en"}],"givenNames":[{"givenName":"Koichiro","givenNameLang":"en"},{"givenName":"弘一郎","givenNameLang":"ja"},{"givenName":"コウイチロウ","givenNameLang":"ja-Kana"},{"givenName":"Kouichiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5570","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80235506","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=80235506"}]},{"creatorNames":[{"creatorName":"Yoshida, Masahiro","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5572","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hatate, Yasuo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5573","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-01-29"}],"displaytype":"detail","filename":"No198_ArsSepActa_5_55(2007).pdf","filesize":[{"value":"417.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文","url":"https://miyazaki-u.repo.nii.ac.jp/record/6262/files/No198_ArsSepActa_5_55(2007).pdf"},"version_id":"63881220-9d4d-40a7-9d59-f639d221a26d"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Extraction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Microcapsule","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Palladium","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Tri-n-octylamine","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Preparation of Effective and Fast Extraction  Media for Palladium (II) Using Microcapsules","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Preparation of Effective and Fast Extraction  Media for Palladium (II) Using Microcapsules","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"5","path":["73","27"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-01-29"},"publish_date":"2021-01-29","publish_status":"0","recid":"6262","relation_version_is_last":true,"title":["Preparation of Effective and Fast Extraction  Media for Palladium (II) Using Microcapsules"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2024-07-04T06:31:46.664619+00:00"}