{"created":"2023-05-15T10:01:38.243291+00:00","id":6261,"links":{},"metadata":{"_buckets":{"deposit":"320aac94-55df-432c-8eaf-7e81163cfe24"},"_deposit":{"created_by":5,"id":"6261","owner":"5","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"6261"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00006261","sets":["73","73:27"]},"author_link":["6242","5574","5570"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-03","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"138","bibliographicPageStart":"125","bibliographicVolumeNumber":"2","bibliographic_titles":[{"bibliographic_title":"Ars Separatoria Acta"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The extraction equilibria of hypophosphorous, phosphorous and phosphoric acids with tri-n-octylamine as an extractant in toluene were measured at 303K. Under these conditions, undissociated acid （A'） reacts with the amine （B） to form various complexes in toluene. The complexes formed and equilibrium constants were estimated by a graphical analysis method. The complexes formed in these systems were found to be A'nB type species for hypophosphorous acid, A'nBm type species for phosphorous acid, （A'B）n type species for phosphoric acid, respectively. The experimental results could be explained by reaction models and equilibrium constants for each acid.","subitem_description_type":"Abstract"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sana, Takashi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"6242","nameIdentifierScheme":"WEKO"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"0000000106573887","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/0000000106573887"}],"affiliationNames":[{"affiliationName":"宮崎大学","affiliationNameLang":"ja"},{"affiliationName":"University of Miyazaki","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Shiomori, Koichiro","creatorNameLang":"en"},{"creatorName":"塩盛, 弘一郎","creatorNameLang":"ja"},{"creatorName":"シオモリ, コウイチロウ","creatorNameLang":"ja-Kana"},{"creatorName":"Shiomori, Kouichiro","creatorNameLang":"en"}],"familyNames":[{"familyName":"Shiomori","familyNameLang":"en"},{"familyName":"塩盛","familyNameLang":"ja"},{"familyName":"シオモリ","familyNameLang":"ja-Kana"},{"familyName":"Shiomori","familyNameLang":"en"}],"givenNames":[{"givenName":"Koichiro","givenNameLang":"en"},{"givenName":"弘一郎","givenNameLang":"ja"},{"givenName":"コウイチロウ","givenNameLang":"ja-Kana"},{"givenName":"Kouichiro","givenNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5570","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"80235506","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=80235506"}]},{"creatorNames":[{"creatorName":"Kawano, Yoshinobu","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"5574","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-01-29"}],"displaytype":"detail","filename":"No114_ARS_2_125(03.pdf","filesize":[{"value":"341.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文","url":"https://miyazaki-u.repo.nii.ac.jp/record/6261/files/No114_ARS_2_125(03.pdf"},"version_id":"d95121b6-93af-4889-8628-349b9eb0de3b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Hypophosphorous acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Phosphorous acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Phosphoric acid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Tri-n-octylamine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Extraction equilibrium","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Extraction Equilibria of Hypophosphorous acid, Phosphorous acid and  Phosphoric acid by Toluene Solution of Tri-n-Octylamine","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Extraction Equilibria of Hypophosphorous acid, Phosphorous acid and  Phosphoric acid by Toluene Solution of Tri-n-Octylamine","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"5","path":["73","27"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-01-29"},"publish_date":"2021-01-29","publish_status":"0","recid":"6261","relation_version_is_last":true,"title":["Extraction Equilibria of Hypophosphorous acid, Phosphorous acid and  Phosphoric acid by Toluene Solution of Tri-n-Octylamine"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2024-07-04T06:31:25.245519+00:00"}