{"created":"2023-05-15T09:58:55.080466+00:00","id":2977,"links":{},"metadata":{"_buckets":{"deposit":"bf51d894-c307-4031-a85c-413796500b7d"},"_deposit":{"created_by":5,"id":"2977","owner":"5","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"2977"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00002977","sets":["73","73:36","73:36:330","73:36:330:314"]},"author_link":["15782","5750","5751","15786","5752"],"item_10002_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"スギ (Cryptomeria japonica) ザイ ノ テルペノイド ノ タンリ オヨビ フェルギノール ノ カガク ヘンカン"}]},"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-10","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"73","bibliographicPageStart":"63","bibliographicVolumeNumber":"33","bibliographic_titles":[{"bibliographic_title":"宮崎大学工学部紀要","bibliographic_titleLang":"ja"},{"bibliographic_title":"Memoirs of Faculty of Engineering, University of Miyazaki","bibliographic_titleLang":"en"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Resin components of Sugi wood were isolated by silica gel column chromatography from the\ntoluene-hexane-soluble fraction of the methanol extract of the heartwood. On the other hand, after the heartwood has been directly extracted with hexane, the resin components were separated from the hexane extract. The isolated yields of β-sitosterol, sanndapacopimarlnal, sandaracopimarinol, and ferruginol from the hexane extract were nearly comparable to those from the toluene-hexane-soluble\nfraction of the methanol extract. Ferruginol. isolated from Sugi wood was benzoylated followed by oxidation with Cr03 in acetic acid to give 12-0-benzoylsugiol, from which sugiol was obtained by methanolysis with anionic ion-exchange resin Amberlite IRA-400 in methanol. The oxidation of\nferruginol with 1.7 equiv. of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in methanol afforded\nsugiol directly. The reaction of sugiol with 3.3 equiv. of DDQ followed by acetylation gave 12-0-acetyl-5,6-dehyqrosugiol, from which 5,6-dehydrosugiol was synthesized. 6,7-Dehydroferruginol was synthesized from 12-0-benzoylsugiol in 60% yield at 3 steps.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"宮崎大学工学部","subitem_publisher_language":"ja"},{"subitem_publisher":"Faculty of Engineering, University of Miyazaki","subitem_publisher_language":"en"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00732558","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05404924","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松井, 隆尚","creatorNameLang":"ja"},{"creatorName":"マツイ, タカナオ","creatorNameLang":"ja-Kana"},{"creatorName":"Matsui, Takanao","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"松下, 洋一","creatorNameLang":"ja"},{"creatorName":"マツシタ, ヨウイチ","creatorNameLang":"ja-Kana"},{"creatorName":"Matsushita, Yoh-ichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Sugamoto, Kazuhiro","creatorNameLang":"en"},{"creatorName":"菅本, 和寛","creatorNameLang":"ja"},{"creatorName":"スガモト, カズヒロ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"矢野, 弘道","creatorNameLang":"ja"},{"creatorName":"ヤノ, ヒロミチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yano, Hiromiti","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-21"}],"displaytype":"detail","filename":"KJ00002428224.pdf","filesize":[{"value":"1.1 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00002428224.pdf","url":"https://miyazaki-u.repo.nii.ac.jp/record/2977/files/KJ00002428224.pdf"},"version_id":"2ca86737-22b5-44e0-9237-0cbd492dd123"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Sugi wood, Methanol extract, Hexane extract, Resin compornents, Chemical conversion","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"スギ(Cryptomeria japonica)材のテルペノイドの単離およびフェルギノールの化学変換","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"スギ(Cryptomeria japonica)材のテルペノイドの単離およびフェルギノールの化学変換","subitem_title_language":"ja"},{"subitem_title":"Isolation of Terpenoids from Sugi (Cryptomeria japonica) Wood and Chemical Conversion of Ferruginol","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"5","path":["73","36","330","314"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2007-06-28"},"publish_date":"2007-06-28","publish_status":"0","recid":"2977","relation_version_is_last":true,"title":["スギ(Cryptomeria japonica)材のテルペノイドの単離およびフェルギノールの化学変換"],"weko_creator_id":"5","weko_shared_id":2},"updated":"2023-09-02T12:59:12.583550+00:00"}