{"created":"2023-05-15T09:58:47.182623+00:00","id":2803,"links":{},"metadata":{"_buckets":{"deposit":"5097c033-5f6d-4dfb-9533-4bae3a3183c6"},"_deposit":{"created_by":5,"id":"2803","owner":"5","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"2803"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00002803","sets":["73","73:36","73:36:330","73:36:330:322"]},"author_link":["6574","6573","6570","25132","6572","14743","14749"],"item_10002_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"ソウホンケイ パルプ ノ セイカガク ハンノウ オヨビ ショクバイ ハンノウ ニヨル バイオ ネンリョウ カ","subitem_alternative_title_language":"ja-Kana"}]},"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-07-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"21","bibliographicPageStart":"17","bibliographicVolumeNumber":"41","bibliographic_titles":[{"bibliographic_title":"宮崎大学工学部紀要","bibliographic_titleLang":"ja"},{"bibliographic_title":"Memoirs of Faculty of Engineering, University of Miyazaki","bibliographic_titleLang":"en"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Bio-fuel has been receiving a great amount of interest from the standpoint of utilizing renewable resources. We have paid much attention on the preparation of the bio-fuels such as 5-hydroxymethyl-2-furfural (HMF) and ethanol which can be derived from the dedydration and the fermentation of hexose (1a), respectively. As a source of 1a, we focused on five kinds of pulps which are made from lignocelluloses such as sabai, wheat straw, kenaf, sweet sorghum bagasse, and bamboo. These pulps were turned into the reducing saccharides (1) by the hydrolysis of the pulp (1 g) with a hydrolytic enzyme (100 mg, acremozyme, cellulase from acremonium) in an acetate buffer solution (60 mL, pH 5.0) at 45℃ for 24 h under vigorous shaking. The 1a was produced in 60-78% of yields whereas pentose (1b) contents was low (11-20%). Ethanol was produced by the usual fermentation of buffer solution of 1 with Saccharomyces cerevisia at 30℃. Total yields of ethanol from the pulps were determined to be 38-59% whereas 1b was recovered without reaction. In the case of the preparation of HMF, the water was remover from the saccharide solution under reduced pressure and then the 1 (500 mg) was subjected to dehydration in MeCN (40 ml) at 140℃ for 24 h in an autoclave using a composite of MgCl2 (31 wt%) with silica gel (1 g) which served as an acid catalyst under dry conditions. HMF was produced from pulp in a 43-55% of total yield.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"宮崎大学工学部","subitem_publisher_language":"ja"},{"subitem_publisher":"Faculty of Engineering, University of Miyazaki","subitem_publisher_language":"en"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00732558","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05404924","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"保田, 昌秀","creatorNameLang":"ja"},{"creatorName":"ヤスダ, マサヒデ","creatorNameLang":"ja-Kana"},{"creatorName":"Yasuda, Masahide","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"中村, 泰久"},{"creatorName":"ナカムラ, ヤスヒサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"三浦, 昭晃","creatorNameLang":"ja"},{"creatorName":"ミウラ, アキテル","creatorNameLang":"ja-Kana"},{"creatorName":"Miura, Akiteru","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"松本, 朋子","creatorNameLang":"ja"},{"creatorName":"マツモト, トモコ","creatorNameLang":"ja-Kana"},{"creatorName":"Matsumoto, Tomoko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"松本, 仁","creatorNameLang":"ja"},{"creatorName":"マツモト, ジン","creatorNameLang":"ja-Kana"},{"creatorName":"Matsumoto, Jin","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"白上, 努","creatorNameLang":"ja"},{"creatorName":"シラガミ, ツトム","creatorNameLang":"ja-Kana"},{"creatorName":"Shiragami, Tsutomu","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Nakamura, Yasuhisa","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"三浦, 昭晃","creatorNameLang":"ja"},{"creatorName":"ミウラ, アキテル","creatorNameLang":"ja-Kana"},{"creatorName":"Miura, Akiteru","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-21"}],"displaytype":"detail","filename":"engineering41_17-21.pdf","filesize":[{"value":"894.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"engineering41_17-21.pdf","url":"https://miyazaki-u.repo.nii.ac.jp/record/2803/files/engineering41_17-21.pdf"},"version_id":"78738500-37f2-413f-9311-caae44398fc4"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Bio-fuels, 5-Hydroxymethyl-2-furfural, Bio-ethanol, Lignocellulose, Acremozyme, MgCl2-silica gel composite","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"草本系パルプの生化学反応および触媒反応によるバイオ燃料化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"草本系パルプの生化学反応および触媒反応によるバイオ燃料化","subitem_title_language":"ja"},{"subitem_title":"Transformation from Herbaceous Pulp to Bio-fuels through Biological and Catalytic Reactions","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"5","path":["73","36","330","322"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-10-25"},"publish_date":"2012-10-25","publish_status":"0","recid":"2803","relation_version_is_last":true,"title":["草本系パルプの生化学反応および触媒反応によるバイオ燃料化"],"weko_creator_id":"5","weko_shared_id":2},"updated":"2023-11-17T04:29:51.891656+00:00"}