@article{oai:miyazaki-u.repo.nii.ac.jp:00002634, author = {田籠, 義貴 and 十川, 喬 and Kameyama, Akihiro and 亀山, 晃弘 and Yokotani, Atsushi and 横谷, 篤至 and Tagomori, Yoshitaka and Togawa, Takashi}, journal = {宮崎大学工学部紀要, Memoirs of Faculty of Engineering, University of Miyazaki}, month = {Aug}, note = {Vacuum-ultraviolet(VUV) radiation has high photon energy so, it has the feature which causes a strong photochemical reaction. Since it has high photon energy, various organic substances can be decomposed by the irradiation of VUV radiation. In this paper, we proposed decomposing toxic substances using vacuum-ultraviolet irradiation. We chose dioxins as a sample toxic substance. Dioxin such as Coplanar polychlorinated biphenyls(PCBs) are very poisonous and difficult to decompose by conventional chemical reactions to decompose. In this paper, Xe_2* lamp was used biphenyl which has a similar structure as PCB as a model substance. By irradiating with Xe_2* lamp, biphenyl was found to be disassembled and it decomposed. The resultants are 2(H_2), 12(C), 14(CH_2), 16(CH_4) and 28(CO), 32(CH_4O) and 44(CO_2) which are substances with less toxicity. In order to discuss a motion of the chlorine contained in PCBs, paradichlorobenzene was also tried to decompose with the Xe_2* lamp. The chlorine was found to disconnect easily and become hydrogen chloride (hydrochloric acid). It is thought that VUV lamp radiation is very effective in weakening the toxicity of dioxins.}, pages = {41--44}, title = {真空紫外光による有害物質の分解過程の計測}, volume = {42}, year = {2013}, yomi = {タゴモリ, ヨシタカ and トガワ, タカシ and カメヤマ, アキヒロ and ヨコタニ, アツシ} }