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Extraction of Amino Acid Esters Using a Pillar[6]arene Carboxylic Acid Derivative as a Novel Acidic Macrocyclic Compound
http://hdl.handle.net/10458/0002001714
http://hdl.handle.net/10458/0002001714851587ec-a9ae-4fef-93bf-fd09b52eeb9b
| 名前 / ファイル | ライセンス | アクション |
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||||||||||||||||
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| 公開日 | 2025-08-27 | |||||||||||||||||||
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| タイトル | Extraction of Amino Acid Esters Using a Pillar[6]arene Carboxylic Acid Derivative as a Novel Acidic Macrocyclic Compound | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
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| 言語 | eng | |||||||||||||||||||
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| 資源タイプ | journal article | |||||||||||||||||||
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| アクセス権 | open access | |||||||||||||||||||
| 著者 |
Ikushima, Yu
× Ikushima, Yu
× 大島, 逹也
WEKO
22923
× 稲田, 飛鳥
WEKO
27557
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| 抄録 | ||||||||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||||||||
| 内容記述 | Pillararenes are a series of novel macrocyclic compounds discovered in the 2000s. However, solvent extraction based on ion exchange using pillararene derivatives is currently limited. Recently, a pillar[6]arene hexaacetic acid derivative (OctP[6]CH2COOH) has been developed as a new acidic extractant. In this study, the extraction of amino acid esters using OctP[6]CH2COOH was investigated. The extraction of tryptophan methyl ester using OctP[6]CH2COOH was much greater than that using the 6-fold equivalent monomer analog. The extraction of more hydrophobic cationic guests was relatively high. This process is based on a proton exchange reaction. The results of slope analysis and Job plot analysis confirmed the formation of a 1:1 complex between OctP[6]CH2COOH and the guest cation. | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
| 書誌情報 |
en : Solvent Extraction Research and Development Japan 巻 32, 号 2, p. 79-87, 発行日 2025 |
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| 出版者 | Japan Association of Solvent Extraction | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
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| 収録物識別子タイプ | EISSN | |||||||||||||||||||
| 収録物識別子 | 21884765 | |||||||||||||||||||
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| 収録物識別子タイプ | ISSN | |||||||||||||||||||
| 収録物識別子 | 13417215 | |||||||||||||||||||
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| 関連タイプ | isVersionOf | |||||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||||
| 関連識別子 | https://doi.org/10.15261/serdj.32.79 | |||||||||||||||||||
| 権利 | ||||||||||||||||||||
| 権利情報 | © Japan Association of Solvent Extraction | |||||||||||||||||||
| 言語 | en | |||||||||||||||||||
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| 出版タイプ | VoR | |||||||||||||||||||
