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  1. 国際連携センター
  1. 国際連携センター
  2. 学術雑誌掲載論文(国際連携センター)

Determination of geochemical parameters that control the spatial distribution of potentially toxic elements released from excavated shale at a temporary storage pit

http://hdl.handle.net/10458/0002001490
http://hdl.handle.net/10458/0002001490
a0c76a79-6098-4e33-98b3-54b449a47b13
名前 / ファイル ライセンス アクション
s10653-025-02577-8.pdf Fulltext (878 KB)
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アイテムタイプ 学術雑誌論文 / Journal Article(1)
公開日 2025-07-21
タイトル
タイトル Determination of geochemical parameters that control the spatial distribution of potentially toxic elements released from excavated shale at a temporary storage pit
言語 en
言語
言語 eng
キーワード
言語 en
キーワード Amorphous iron
キーワード
言語 en
キーワード Colloid
キーワード
言語 en
キーワード Estimation error
キーワード
言語 en
キーワード Excavated rock
キーワード
言語 en
キーワード Spatial distribution
資源タイプ
資源タイプ journal article
アクセス権
アクセス権 open access
著者 Suzuki, Shoji

× Suzuki, Shoji

en Suzuki, Shoji
Meiji University

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Miura, Toshihiko

× Miura, Toshihiko

en Miura, Toshihiko
Obayashi Corporation

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伊藤, 健一

× 伊藤, 健一

WEKO 21030
e-Rad_Researcher 90524695

ja 伊藤, 健一
宮崎大学

ja-Kana イトウ, ケンイチ

en Ito, Kenichi
University of Miyazaki

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Katoh, Masahiko

× Katoh, Masahiko

en Katoh, Masahiko
Meiji University

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抄録
内容記述タイプ Abstract
内容記述 Large quantities of rocks naturally containing potentially toxic elements (PTEs) are generally excavated from urbanized and mountainous areas for construction purposes and are subjected to treatments (e.g., chemical immobilization) so that they can be re-used. To design such treatments, it is imperative to determine the total PTE amounts released from the excavated rocks and consider their spatial distribution. Within this context, the present study aimed to clarify (i) the spatial distribution of PTE contents released from 100 m3 of excavated shale deposited in a temporary storage pit, and (ii) the geochemical parameters that control such distribution. A total of 50 shale samples were collected from a temporary storage pit of rocks. These samples were subjected to the analysis for the determination of the released and total PTE amounts, and other chemical properties. No linear relationship was detected between the released and total PTE amounts. An error of ± 30% was estimated based on a sample of 10 rocks. The geochemical parameters controlling the PTE contents released from the excavated shale differed depending on PTE types. The release of arsenic and selenium was mainly controlled by the amount of amorphous iron, while that of lead and chromium was controlled by the amount of inorganic colloidal particles with size under 0.45-μm. This study suggested that the preparation of 10 mixed rock samples collected from temporary storage pits leads to an estimation of released PTE amounts with a 30% error. In addition, the actual PTE amount released from excavated rocks containing high and low amounts of amorphous iron and inorganic colloidal particles, respectively, would differ little from the estimated amounts.
言語 en
書誌情報 en : Environmental Geochemistry and Health

巻 47, p. 259, 発行日 2025-07-10
出版者
出版者 Springer Science and Business Media LLC
言語 en
ISSN
収録物識別子タイプ PISSN
収録物識別子 02694042
ISSN
収録物識別子タイプ EISSN
収録物識別子 15732983
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 https://doi.org/10.1007/s10653-025-02577-8
著者版フラグ
出版タイプ VoR
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