{"created":"2023-05-15T12:15:28.279240+00:00","links":{},"metadata":{"_buckets":{"deposit":"e0843422-1b60-41ee-a4f1-5446550636af"},"_deposit":{"id":"1729.1","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"1729.1"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00001729.1","sets":["71:25","71:25:90","71:25:90:95","71:25:90:95:235"]},"author_link":["632","10190","10191"],"item_10002_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction","subitem_alternative_title_language":"en"}]},"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-09-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"7","bibliographicPageStart":"1","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"宮崎大学教育文化学部紀要. 自然科学","bibliographic_titleLang":"ja"},{"bibliographic_title":"Memoirs of the Faculty of Education and Culture, Miyazaki University. Natural science","bibliographic_titleLang":"en"}]}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"9,1O-Dicyanoanthracene (DCA)-sensitized cycloreversion of 1,5-diphenylbicyclo-[3.2.0]hept-6-ene (1a) and 5-(1-naphthy1)-4-phenyl bicyclo[3.2.0] hept-6-ene (1b) to 1,4-diphenylcyclohepta- 1,3-diene (2a) and 1-(1-naphthyl)-4-phenylcyclohepta-1,3-diene (2b), respectively, occurred with high quantum yield in acetonitrile or benzene at room temperature. The mechanism is discussed in terms of electron transfer from 1 to the excited singlet state of DCA. The cycloreversion of radical cation of 1 (1+) occurred rapidly even at 77K in pulse radiolysis and γ -radiolysis. It is suggested that cycloreversion of 1+ occurs in the mechanism involving cleavage of Cl-C5 σ -bond and cyclic reaction of Cl-C5 σ-orbitals and C6-C7 π-orbitals.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"宮崎大学教育文化学部","subitem_publisher_language":"ja"},{"subitem_publisher":"The Faculty of Education and Culture, University of Miyazaki","subitem_publisher_language":"en"}]},"item_10002_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11403456","subitem_source_identifier_type":"NCID"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13454021","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nakabayashi, Kenichi","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Hashiguchi, Norifumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuda, Yusaku","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-21"}],"displaytype":"detail","filename":"KJ00002440005.pdf","filesize":[{"value":"395.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00002440005.pdf","url":"https://miyazaki-u.repo.nii.ac.jp/record/1729.1/files/KJ00002440005.pdf"},"version_id":"965fd980-d233-43b7-a39c-2b927f7fa32c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"2","path":["25","90","95","235"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-03-24"},"publish_date":"2008-03-24","publish_status":"0","recid":"1729.1","relation_version_is_last":true,"title":["Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-07-17T02:09:48.800732+00:00"}