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Mechanism of copper(II) adsorption by polyvinyl polyacrylate
http://hdl.handle.net/10458/1010
http://hdl.handle.net/10458/101067024e2b-a00a-4959-a935-19b374ee247e
| 名前 / ファイル | ライセンス | アクション |
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JApplPolymSci-102-5372-2006.pdf (337.3 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2007-12-05 | |||||
| タイトル | ||||||
| タイトル | Mechanism of copper(II) adsorption by polyvinyl polyacrylate | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| キーワード | Copper adsorption, polyvinyl polyacrylate, ESR, magnetic susceptibility, copper dimer | |||||
| 資源タイプ | ||||||
| 資源タイプ | journal article | |||||
| 著者 |
Nakajima, Akira
× Nakajima, Akira× Sakai, Naoko× Yamauchi, Jun |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The mechanism of copper adsorption by polyvinyl polyacrylate （PVPA） was examined by using ESR and magnetic measurements. The copper adsorption by PVPA was obeyed Langmuir adsorption isotherm with the maximum adsorption amounts of 4.17 mmol/g adsorbent, being larger than those of uranium adsorption. Though copper in the solution was completely adsorbed by the resin above pH 4, the ESR intensity was remained low level and only increased above pH 8. The ESR spectrum of Cu（II） ion in PVPA are axial type with tetragonally distorted octahedral symmetry, having parameters of g// = 2.361, g⊥= 2.057, |A//| = 14.0 mcm−1 （pH 5）, and g// = 2.329, g⊥= 2.058, |A//| = 16.2 mcm−1 , |A⊥| = 2.7 mcm−1 （pH 9）. The absorption peaks originated from Cu（II）-Cu（II） dimer was also observed （pH 5）. The paramagnetic susceptibility of PVPA adsorbed Cu（II） ion at pH 5 explained by the dimer model with |J| = 220 K. These results suggested that most of copper was adsorbed and formed dimer in PVPA, being similar as that in Cu（II）-acetate monohydrate. |
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| 言語 | en | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Copyright© Wiley Periodicals,Inc.or copyright owner as specified in the Journal. | |||||
| 言語 | en | |||||
| 書誌情報 |
en : Journal of applied polymer science 巻 102, 号 6, p. 5372-5377, 発行日 2006-12-15 |
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| 出版者 | ||||||
| 出版者 | John Wiley & Sons | |||||
| 言語 | en | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 00218995 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00693605 | |||||
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| 出版タイプ | AM | |||||
