{"created":"2023-05-15T09:56:31.915187+00:00","id":133,"links":{},"metadata":{"_buckets":{"deposit":"dce9e915-0709-4194-9eb7-26bfc37595fd"},"_deposit":{"created_by":5,"id":"133","owner":"5","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"133"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00000133","sets":["71","71:24"]},"author_link":["450","455","387","451","6","454"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1987-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"549","bibliographicPageStart":"545","bibliographicVolumeNumber":"60","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Extraction behavior of alkali and alkaline earth metal cations was investigated with a new extractant derived from polyethylene glycol mono[4-(1,1,3,3-tetramethylbutyl)phenyl]ether (Triton X-100; average number of oxyethylene group, 10) by introducing a phenolic(2-hydroxy-5-nitrobenzyl) group at the hydroxyl terminal of the polyethylene glycol chain. Alkali metal cations were extracted into 1,2-dichloroethane by forming 1:1 complex with the extractant. The overall extraction constant sequence was K^+(10^−9.15)>Rb^+(10^−9.26)>Cs^+ (10^−9.28)>Na^+ (10^−10.08)>Li^+(10^−10.36). The selectivity for K^+, Na^+, and Li^+ was discussed by comparing the extraction behavior with a mixture of nonionic surfactant or dicyclohexano-18-crown-6 and a proton-dissociable lipophilic dye. For alkaline earth metal cations, the extractability decreased in the order Ba^2+>Sr^2+>Ca^2+>>Mg^2+. The metal extractability strongly depended on the nature of the anion in the aqueous phase.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会","subitem_publisher_language":"ja"},{"subitem_publisher":"The Chemical Society of Japan","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C) 1987 The Chemical Society of Japan","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00092673","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Sakai, Yukio","creatorNameLang":"en"},{"creatorName":"境, 幸夫","creatorNameLang":"ja"},{"creatorName":"サカイ, 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