{"created":"2023-05-15T10:40:13.869322+00:00","links":{},"metadata":{"_buckets":{"deposit":"1f113dab-5ae3-4422-a32e-11cffd5124a8"},"_deposit":{"id":"133.1","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"133.1"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00000133.1","sets":["71:24"]},"author_link":["6","450","451","452","454","455","456"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1987-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"549","bibliographicPageStart":"545","bibliographicVolumeNumber":"60","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Extraction behavior of alkali and alkaline earth metal cations was investigated with a new extractant derived from polyethylene glycol mono[4-(1,1,3,3-tetramethylbutyl)phenyl]ether (Triton X-100; average number of oxyethylene group, 10) by introducing a phenolic(2-hydroxy-5-nitrobenzyl) group at the hydroxyl terminal of the polyethylene glycol chain. Alkali metal cations were extracted into 1,2-dichloroethane by forming 1:1 complex with the extractant. The overall extraction constant sequence was K^+(10^−9.15)>Rb^+(10^−9.26)>Cs^+ (10^−9.28)>Na^+ (10^−10.08)>Li^+(10^−10.36). The selectivity for K^+, Na^+, and Li^+ was discussed by comparing the extraction behavior with a mixture of nonionic surfactant or dicyclohexano-18-crown-6 and a proton-dissociable lipophilic dye. For alkaline earth metal cations, the extractability decreased in the order Ba^2+>Sr^2+>Ca^2+>>Mg^2+. The metal extractability strongly depended on the nature of the anion in the aqueous phase.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会","subitem_publisher_language":"ja"},{"subitem_publisher":"The Chemical Society of Japan","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C) 1987 The Chemical Society of Japan","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00092673","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"境, 幸夫","creatorNameLang":"ja"},{"creatorName":"サカイ, ユキオ","creatorNameLang":"ja-Kana"},{"creatorName":"境, 幸夫","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"新村, 正広","creatorNameLang":"ja"},{"creatorName":"シンムラ, マサヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大塚, 肇","creatorNameLang":"ja"},{"creatorName":"オオツカ, ハジメ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"高木, 誠","creatorNameLang":"ja"},{"creatorName":"タカギ, マコト","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shinmura, Masahiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Otsuka, Hajime","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takagi, Makoto","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-21"}],"displaytype":"detail","filename":"ski_1987.pdf","filesize":[{"value":"451.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ski_1987.pdf","url":"https://miyazaki-u.repo.nii.ac.jp/record/133.1/files/ski_1987.pdf"},"version_id":"10639386-40fc-4eb1-b24b-f507456da14a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The Solvent Extraction of Alkali and Alkaline Earth Metal Ions with Nonionic and Ionic Surfactants Having Poly(oxyethylene) Chain","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The Solvent Extraction of Alkali and Alkaline Earth Metal Ions with Nonionic and Ionic Surfactants Having Poly(oxyethylene) Chain","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"2","path":["24"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-05-14"},"publish_date":"2014-05-14","publish_status":"0","recid":"133.1","relation_version_is_last":true,"title":["The Solvent Extraction of Alkali and Alkaline Earth Metal Ions with Nonionic and Ionic Surfactants Having Poly(oxyethylene) Chain"],"weko_creator_id":"2","weko_shared_id":2},"updated":"2023-07-29T10:37:08.160325+00:00"}