{"created":"2023-05-15T09:56:31.618665+00:00","id":125,"links":{},"metadata":{"_buckets":{"deposit":"56aff25c-2c7c-4c7e-8bf7-6bcd23791200"},"_deposit":{"created_by":5,"id":"125","owner":"5","owners":[5],"pid":{"revision_id":0,"type":"depid","value":"125"},"status":"published"},"_oai":{"id":"oai:miyazaki-u.repo.nii.ac.jp:00000125","sets":["71:24"]},"author_link":["392","388","387","6","386"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1986-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"384","bibliographicPageStart":"381","bibliographicVolumeNumber":"59","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The extraction of alkaline earth metal ions has been investigated using a mixture of polyethylene glycol mono-p-nonylphenyl ether (PEGP; average number of oxyethylene group, 10) and 4-(1,1-dimethyl-3,3-dimethylbutyl)-2,5-dinitrophenol (2,5-dinitro-4-t-octylphenol, DNP; HL) in_1,2-dichloroethane. The metal extraction takes place with one molecule of deprotonated DNP (L^−) and an extraneous monoanion (X^−) for neutralization of the dicationic charge of the metal ion. The ease of extraction generally follows the order, Ba^2+>Sr^2+>Ca^2+>>Mg^2+. The nature of the anion present in the aqueous phase strongly affects the extractability. For barium, the extractability decreases in the order ClO_4^−>SCN^−>I^−>Cl^−>NO_3^−. The composition of the extracted complexes for barium and strontium ions proportional to the metal is metal : PEGP : L^− : X^−=1 : 1 : 1 : 1. The overall extraction constants were estimated.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会","subitem_publisher_language":"ja"},{"subitem_publisher":"The Chemical Society of Japan","subitem_publisher_language":"en"}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"(C) 1986 The Chemical Society of Japan","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00092673","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"Sakai, Yukio","creatorNameLang":"en"},{"creatorName":"境, 幸夫","creatorNameLang":"ja"},{"creatorName":"サカイ, ユキオ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"中村, 博","creatorNameLang":"ja"},{"creatorName":"ナカムラ, ヒロシ","creatorNameLang":"ja-Kana"},{"creatorName":"Nakamura, Hiroshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"高木, 誠","creatorNameLang":"ja"},{"creatorName":"タカギ, マコト","creatorNameLang":"ja-Kana"},{"creatorName":"Takagi, Makoto","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"上野, 景平","creatorNameLang":"ja"},{"creatorName":"ウエノ, ケイヘイ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"","affiliationNameIdentifierScheme":"ISNI","affiliationNameIdentifierURI":"http://www.isni.org/isni/"}],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"高木, 誠","creatorNameLang":"ja"},{"creatorName":"タカギ, マコト","creatorNameLang":"ja-Kana"},{"creatorName":"Takagi, Makoto","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ueno, Keihei","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-06-21"}],"displaytype":"detail","filename":"ski_1986.pdf","filesize":[{"value":"280.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ski_1986.pdf","url":"https://miyazaki-u.repo.nii.ac.jp/record/125/files/ski_1986.pdf"},"version_id":"e1ee3d05-5a9c-4d06-9732-5ac4f4f85f54"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The Solvent Extraction of Alkaline Earth Metal Ions with Nonionic Surfactants","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The Solvent Extraction of Alkaline Earth Metal Ions with Nonionic Surfactants","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"5","path":["24"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-05-14"},"publish_date":"2014-05-14","publish_status":"0","recid":"125","relation_version_is_last":true,"title":["The Solvent Extraction of Alkaline Earth Metal Ions with Nonionic Surfactants"],"weko_creator_id":"5","weko_shared_id":-1},"updated":"2023-12-26T05:25:22.977626+00:00"}