WEKO3
アイテム
{"_buckets": {"deposit": "acea6384-10e6-45eb-8edc-71961785009d"}, "_deposit": {"created_by": 5, "id": "1729", "owner": "5", "owners": [5], "pid": {"revision_id": 0, "type": "depid", "value": "1729"}, "status": "published"}, "_oai": {"id": "oai:miyazaki-u.repo.nii.ac.jp:00001729", "sets": ["95", "235", "25", "71", "90"]}, "author_link": ["632", "10190", "10191"], "item_10002_alternative_title_1": {"attribute_name": "その他(別言語等)のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction", "subitem_alternative_title_language": "en"}]}, "item_10002_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2003-09-30", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "7", "bibliographicPageStart": "1", "bibliographicVolumeNumber": "9", "bibliographic_titles": [{"bibliographic_title": "宮崎大学教育文化学部紀要. 自然科学", "bibliographic_titleLang": "ja"}, {"bibliographic_title": "Memoirs of the Faculty of Education and Culture, Miyazaki University. Natural science", "bibliographic_titleLang": "en"}]}]}, "item_10002_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "9,1O-Dicyanoanthracene (DCA)-sensitized cycloreversion of 1,5-diphenylbicyclo-[3.2.0]hept-6-ene (1a) and 5-(1-naphthy1)-4-phenyl bicyclo[3.2.0] hept-6-ene (1b) to 1,4-diphenylcyclohepta- 1,3-diene (2a) and 1-(1-naphthyl)-4-phenylcyclohepta-1,3-diene (2b), respectively, occurred with high quantum yield in acetonitrile or benzene at room temperature. The mechanism is discussed in terms of electron transfer from 1 to the excited singlet state of DCA. The cycloreversion of radical cation of 1 (1+) occurred rapidly even at 77K in pulse radiolysis and γ -radiolysis. It is suggested that cycloreversion of 1+ occurs in the mechanism involving cleavage of Cl-C5 σ -bond and cyclic reaction of Cl-C5 σ-orbitals and C6-C7 π-orbitals.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10002_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "宮崎大学教育文化学部", "subitem_publisher_language": "ja"}, {"subitem_publisher": "The Faculty of Education and Culture, University of Miyazaki", "subitem_publisher_language": "en"}]}, "item_10002_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA11403456", "subitem_source_identifier_type": "NCID"}]}, "item_10002_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "13454021", "subitem_source_identifier_type": "ISSN"}]}, "item_10002_text_25": {"attribute_name": "BIBID", "attribute_value_mlt": [{"subitem_text_value": "TC00001722"}]}, "item_10002_text_26": {"attribute_name": "登録日", "attribute_value_mlt": [{"subitem_text_value": "2008/03/24"}]}, "item_10002_textarea_24": {"attribute_name": "来歴", "attribute_value_mlt": [{"subitem_textarea_value": "Submitted by dspace dspace (lib-ir@of.miyazaki-u.ac.jp) on 2008-03-17T12:09:15Z\nNo. of bitstreams: 2\nlicence.pdf: 49491 bytes, checksum: 4945315b1d94f99a74f3373a9efb7316 (MD5)\nKJ00002440005.pdf: 330232 bytes, checksum: d56f81a1031915e01a406cbe813c2806 (MD5)"}, {"subitem_textarea_value": "Approved for entry into archive by dspace dspace(lib-ir@of.miyazaki-u.ac.jp) on 2008-03-24 (GMT) No. of bitstreams: 2\nlicence.pdf: 49491 bytes, checksum: 4945315b1d94f99a74f3373a9efb7316 (MD5)\nKJ00002440005.pdf: 330232 bytes, checksum: d56f81a1031915e01a406cbe813c2806 (MD5)"}, {"subitem_textarea_value": "Made available in DSpace on 2008-03-24 (GMT). No. of bitstreams: 2\nlicence.pdf: 49491 bytes, checksum: 4945315b1d94f99a74f3373a9efb7316 (MD5)\nKJ00002440005.pdf: 330232 bytes, checksum: d56f81a1031915e01a406cbe813c2806 (MD5)\n Previous issue date: 2003-09-30"}]}, "item_10002_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nakabayashi, Kenichi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "632", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60201670", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60201670"}]}, {"creatorNames": [{"creatorName": "Hashiguchi, Norifumi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "10190", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuda, Yusaku", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "10191", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2020-06-21"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "KJ00002440005.pdf", "filesize": [{"value": "395.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 395800.0, "url": {"label": "KJ00002440005.pdf", "url": "https://miyazaki-u.repo.nii.ac.jp/record/1729/files/KJ00002440005.pdf"}, "version_id": "40901f2e-ed25-4ec9-9b3e-7f32b360fe6e"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction", "subitem_title_language": "en"}]}, "item_type_id": "10002", "owner": "5", "path": ["71", "25", "90", "95", "235"], "permalink_uri": "http://hdl.handle.net/10458/1396", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2008-03-24"}, "publish_date": "2008-03-24", "publish_status": "0", "recid": "1729", "relation": {}, "relation_version_is_last": true, "title": ["Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction"], "weko_shared_id": 2}
Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction
http://hdl.handle.net/10458/1396
http://hdl.handle.net/10458/1396ed5d385d-8579-4dfa-827f-6d72a79260b4
名前 / ファイル | ライセンス | アクション |
---|---|---|
KJ00002440005.pdf (395.8 kB)
|
|
Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2008-03-24 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Cycloreversion of 1,5-Diarylcyclobutene in a Photosensitized Reaction | |||||
言語 | en | |||||
著者 |
Nakabayashi, Kenichi
× Nakabayashi, Kenichi× Hashiguchi, Norifumi× Matsuda, Yusaku |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 9,1O-Dicyanoanthracene (DCA)-sensitized cycloreversion of 1,5-diphenylbicyclo-[3.2.0]hept-6-ene (1a) and 5-(1-naphthy1)-4-phenyl bicyclo[3.2.0] hept-6-ene (1b) to 1,4-diphenylcyclohepta- 1,3-diene (2a) and 1-(1-naphthyl)-4-phenylcyclohepta-1,3-diene (2b), respectively, occurred with high quantum yield in acetonitrile or benzene at room temperature. The mechanism is discussed in terms of electron transfer from 1 to the excited singlet state of DCA. The cycloreversion of radical cation of 1 (1+) occurred rapidly even at 77K in pulse radiolysis and γ -radiolysis. It is suggested that cycloreversion of 1+ occurs in the mechanism involving cleavage of Cl-C5 σ -bond and cyclic reaction of Cl-C5 σ-orbitals and C6-C7 π-orbitals. | |||||
言語 | en | |||||
書誌情報 |
ja : 宮崎大学教育文化学部紀要. 自然科学 en : Memoirs of the Faculty of Education and Culture, Miyazaki University. Natural science 巻 9, p. 1-7, 発行日 2003-09-30 |
|||||
出版者 | ||||||
言語 | ja | |||||
出版者 | 宮崎大学教育文化学部 | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | The Faculty of Education and Culture, University of Miyazaki | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13454021 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11403456 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |